Chemistry (4th Edition)

Published by McGraw-Hill Publishing Company
ISBN 10: 0078021529
ISBN 13: 978-0-07802-152-7

Chapter 14 - Section 14.2 - Dependence of Reaction Rate on Reactant Concentration - Checkpoint - Page 619: 14.2.1

Answer

e) is the correct answer.

Work Step by Step

1. $rate = k[A]^x[B]^y$ 2. Divide rate1 by rate2: $$\frac{rate_1}{rate_2} = \frac{k(0.12)^x(0.010)^y}{k(0.36)^x(0.010)^y} =\frac{(0.12)^x}{(0.36)^x} = (1/3)^x$$ $$\frac{rate_1}{rate_2} = \frac{2.2 \times 10^{-3} }{6.6 \times 10^{-3}} = 1/3$$ $$ (1/3)^x = 1/3$$ x must be equal to 1. 3. Do the same thing for 1 and 3: $$\frac{rate_1}{rate_2} = \frac{k(0.12)^x(0.010)^y}{k(0.12)^x(0.020)^y} =\frac{(0.010)^y}{(0.020)^y} = (1/2)^y$$ $$\frac{rate_1}{rate_2} = \frac{2.2 \times 10^{-3} }{2.2 \times 10^{-3}} = 1$$ $$ (1/2)^y = 1$$ y must be qual to 0. $$rate = k[A]^1[B]^0 = k[A]$$
Update this answer!

You can help us out by revising, improving and updating this answer.

Update this answer

After you claim an answer you’ll have 24 hours to send in a draft. An editor will review the submission and either publish your submission or provide feedback.