Chemistry 12th Edition

Published by McGraw-Hill Education
ISBN 10: 0078021510
ISBN 13: 978-0-07802-151-0

Chapter 6 - Thermochemistry - Questions & Problems - Page 267: 6.101

Answer

$\Delta H^{\circ}_{f} =+ 1.9 kJ/mol $

Work Step by Step

The equation for the enthalpy of formation of diamond is $C_{graphite} → C_{diamond}$. Equation 1: $C_{(graphite)} + O_{2(g)} →CO_{2(g)}$ $ H^{\circ}rxn = - 393.5 kJ/mol$ Equation 2: $C_{(diamond)} + O_{2(g)} →CO_{2(g)}$ $ H^{\circ}rxn = - 395.4 kJ/mol$ By adding equation 1 with the reversed equation of 2, we get the enthalpy of formation equation $C_{graphite} → C_{diamond}$. $\Delta H^{\circ}_{f} = - 393.5 – (- 395.4) kJ/mol = + 1.9 kJ/mol $
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