Chemistry 12th Edition

Published by McGraw-Hill Education
ISBN 10: 0078021510
ISBN 13: 978-0-07802-151-0

Chapter 13 - Chemical Kinetics - Questions & Problems - Page 615: 13.88

Answer

$k_1 = 0.08949 min^{-1}$

Work Step by Step

A first order reaction is 35.5% completed in (t=) 4.9 minutes. Let initial concentration of reactant, $a_o$ = 100 Concentration of reaction left after 4.9 minutes, $a_t$= 100 - 35.5 = 64.5 Using the integrated rate law for first order reaction, $$ k_1 = \frac{1}{t} \times ln (\frac{a_o}{a_t})$$ Substituting the values in the above equation, $$ k_1 = \frac{1}{4.9 min} \times ln (\frac{100}{64.5})$$ On solving we get, $$k_1 = 0.08949 min^{-1}$$
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