Chemistry 10th Edition

Published by Brooks/Cole Publishing Co.
ISBN 10: 1133610668
ISBN 13: 978-1-13361-066-3

Chapter 4 - The Structure of Atoms - Exercises - Electromagnetic Radiation - Page 167: 56

Answer

$a) 3.18\times 10^{-18} Joule $ ; UV Region $b) 7.82\times 10^{-20} Joule $ ; IR Region $c) 3.60 \times 10^{-21} Joule $; IR Region

Work Step by Step

Energy of a Photon, $E = h\nu$ where $h = Planck Constant = 6.626 \times 10^{-34} Joule-sec$ & $\nu = frequency$ a) Here, $\nu = 4.80 \times 10^{15} S^{-1} $ Hence, $E = 6.626\times 10^{-34}\times 4.80 \times 10^{15} Joule = 3.18 \times 10^{-18} $Joule per photon Also, frequency $\nu = \frac{c}{\lambda} $ where c = speed of light in vacuum = $3 \times 10^{8} m/s$ and $\lambda $ = wavelength of the radiation Hence, $\lambda = \frac{c}{\nu}$ Here, $\lambda = \frac{3\times 10^{8}}{4.80\times 10^{15}}$ = $6.25\times 10^{-8} m$ = 62.5 nm . This wavelength of radiation lies in the UV region. b) $\nu = 1.18 \times 10^{14} s^{-1}$ $\therefore E = 6.626\times 10^{-34}\times 1.18 \times 10^{14} = 7.82 \times 10^{-20} Joule $ and $\lambda = \frac{3\times 10^{8}}{1.18\times 10^{14}} = 2.54 \times 10^{-6}m = 2.54 \mu m$. This wavelength of radiation lies in IR region. c) b) $\nu = 5.44 \times 10^{12} s^{-1}$ $\therefore E = 6.626\times 10^{-34}\times 5.44 \times 10^{12} Joule = 3.6 \times 10^{-21} J$ and $\lambda = \frac{3\times 10^{8}}{5.44\times 10^{12}} = 5.51 \times 10^{-5}m = 55.1 \mu m$. This wavelength of radiation also lies in IR region.
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