Chemistry 10th Edition

Published by Brooks/Cole Publishing Co.
ISBN 10: 1133610668
ISBN 13: 978-1-13361-066-3

Chapter 4 - The Structure of Atoms - Exercises - Electromagnetic Radiation - Page 167: 55

Answer

a)$3.18\times10^{-18}Joule$ ; UV Region b)$7.82\times10^{-20}Joule$ ; IR Region c)$3.60\times10^{-21}Joule$; IR Region

Work Step by Step

Energy of a Photon, $E=h\nu$ where $h=Planck Constant=6.626\times10^{-34}Joule.sec$ & $\nu$=frequency a) Here, $\nu=4.80\times10^{15}S^{-1}$ Hence, $E=6.626\times10^{-34}\times4.80\times10^{15}Joule=3.18\times10^{-18}Joule per photon$ Also, frequency $\nu = \frac{c}{\lambda}$ where c = speed of light in vacuum = $3\times10^{8}m/s$ and $\lambda$ = wavelength of the radiation Hence, $\lambda = \frac{c}{\nu}$ Here, $\lambda= \frac{3\times10^{8}}{4.80\times10^{15}} = 6.25\times10^{-8}m = 62.5 nm $. This wavelength of radiation lies in the UV region. b) $\nu=1.18\times10^{14}S^{-1}$ $\therefore E=6.626\times10^{-34}\times1.18\times10^{14}=7.82\times10^{-20}Joule$ and $\lambda=\frac{3\times10^{8}}{1.18\times10^{14}} = 2.54\times10^{-6}m = 2.54\mu m.$ This wavelength of radiation lies in IR region. c) $\nu=5.44\times10^{12}S^{-1}$ $\therefore E=6.626\times10^{-34}\times5.44\times10^{12}Joule=3.6\times10^{-21}J$ and $\lambda=\frac{3\times10^{8}}{5.44\times10^{12}}=5.51\times10^{-5}m=55.1\mu m.$ This wavelength of radiation also lies in IR region.
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