Answer
$S$ does not span $R^2$.
Work Step by Step
The set $S=\{(-3,2)\}$ is not a basis for $R^2$ because $S$ does not span $R^2$. For example, suppose the vector $(-3,0)\in R^2$ and writing it as a linear combination of the elements of $S$, we get
$$(-3,0)=c(-3,2), \quad c\in R.$$
Which yields the following system of equations
$$-3c=-3, \quad 2c=0.$$
It is easy to note that the above system is in-consistent, since $c=1$ the solution of the first equation does not satisfy the second equation.