Answer
$5$ dimes and $9$ quarters.
Work Step by Step
Let $x$ be the number of dimes he had. Then the number of quarters is $14-x$.
Then our equation is:
$0.1x+0.25(14-x)=2.75\\0.1x+3.5-0.25x=2.75\\0.75=0.15x\\x=5$
Thus, he had $5$ dimes and $14-5=9$ quarters.