Materials Science and Engineering: An Introduction

Published by Wiley
ISBN 10: 1118324579
ISBN 13: 978-1-11832-457-8

Chapter 17 - Corrosion and Degradation of Materials - Questions and Problems - Page 721: 17.2a

Answer

The possible oxidation and reduction half-reactions when magnesium is immersed in various solutions are as follows: (i). In HCl, possible reactions are Mg → Mg2+ + 2e- (oxidation) 2H+ + 2e- → H2 (reduction) (ii) In an HCl solution containing dissolved oxygen, possible reactions are Mg → Mg2+ + 2e- (oxidation) 4H+ + O2 + 4e- → 2H2O (reduction) (iii) In an HCl solution containing dissolved oxygen and Fe2+ ions, possible reactions are Mg → Mg2+ + 2e- (oxidation) 4H+ + O2 + 4e- → 2H2O (reduction) Fe2+ + 2e-→ Fe (reduction)

Work Step by Step

The possible oxidation and reduction half-rections when magnesium is immersed in various solutions are as follows: (i). In HCl, possible reactions are Mg → Mg2+ + 2e- (oxidation) 2H+ + 2e- → H2 (reduction) (ii) In an HCl solution containing dissolved oxygen, possible reactions are Mg → Mg2+ + 2e- (oxidation) 4H+ + O2 + 4e- → 2H2O (reduction) (iii) In an HCl solution containing dissolved oxygen and Fe2+ ions, possible reactions are Mg → Mg2+ + 2e- (oxidation) 4H+ + O2 + 4e- → 2H2O (reduction) Fe2+ + 2e-→ Fe (reduction)
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