- Juliette Binoche as Vianne Rocher
- Victoire Thivisol as Anouk Rocher, Vianne's daughter (voiced by Sally Taylor-Isherwood because Victoire's French accent made her difficult to understand)
- Judi Dench as Armande Voizin, Caroline's mother
- Alfred Molina as Comte de Reynaud, the mayor
- Lena Olin as Joséphine Muscat, Serge's abused wife
- Johnny Depp as Roux, a self-described "river-rat" and Vianne's lover
- Hugh O'Conor as Père Henri, village priest
- Carrie-Anne Moss as Caroline Clairmont, Armande's daughter
- Aurélien Parent-Koenig as Luc Clairmont, Caroline's son
- Peter Stormare as Serge Muscat, café owner
- Hélène Cardona as Françoise "Fuffi" Drou, beauty shop proprietor
- Antonio Gil as Jean-Marc Drou
- Elisabeth Commelin as Yvette Marceau, woman who buys chocolates as an aphrodisiac
- Ron Cook as Alphonse Marceau, Yvette's husband
- Leslie Caron as Madame Audel, village widow whose husband died in World War I
- John Wood as Guillaume Blérot, who carries a long-time yearning for Madame Audel
- Michèle Gleizer as Madame Rivet, village woman who works for the Comte
- Dominique MacAvoy as Madame Pouget, village woman
- Arnaud Adam as Georges Rocher, Vianne's father
- Christianne Oliveira as Chitza Rocher, Vianne's mother
- Tatyana Yassukovich, the narrator
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