- Mel Gibson as William Wallace
- James Robinson as young William Wallace
- Sophie Marceau as Princess Isabella of France
- Angus Macfadyen as Robert the Bruce
- Patrick McGoohan as King Edward "Longshanks"
- Catherine McCormack as Murron MacClannough
- Mhairi Calvey as young Murron MacClannough
- Brendan Gleeson as Hamish
- Andrew Weir as young Hamish
- Peter Hanly as Prince Edward
- James Cosmo as Campbell
- David O'Hara as Stephen of Ireland
- Ian Bannen as Bruce's father
- Seán McGinley as MacClannough
- Brian Cox as Argyle Wallace
- Sean Lawlor as Malcolm Wallace
- Sandy Nelson as John Wallace
- Stephen Billington as Phillip
- John Kavanagh as Craig
- Alun Armstrong as Mornay
- John Murtagh as Lochlan
- Tommy Flanagan as Morrison
- Donal Gibson as Stewart
- Jeanne Marine as Nicolette
- Michael Byrne as Smythe
- Malcolm Tierney as Magistrate
- Bernard Horsfall as Balliol
- Peter Mullan as Veteran
- Gerard McSorley as Cheltham
- Richard Leaf as Governor of York
- Mark Lees as Old Crippled Scotsman
- Tam White as MacGregor
- Jimmy Chisholm as Faudron
- David Gant as the Royal Magistrate
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