Physics for Scientists and Engineers: A Strategic Approach with Modern Physics (3rd Edition)

Published by Pearson
ISBN 10: 0321740904
ISBN 13: 978-0-32174-090-8

Chapter 39 - Wave Functions and Uncertainty - Exercises and Problems - Page 1177: 37

Answer

a) $0.271\%$ b) $31.8\%$

Work Step by Step

The given wave function for the electron is normalized, and we know that the probability of finding the electron in a given region is the integral of the square of the wave function $ |\psi(x)|^2 $ over that region. $$ \psi(x) = \begin{cases} 0 & x < 0 \; \text{nm} \\ (1.414 \; \text{nm}^{-1/2}) e^{-x/(1.0 \; \text{nm})} & x \geq 0 \; \text{nm} \end{cases} $$ $$\color{blue}{\bf [a]}$$ The probability of finding the electron in a $\delta x=\rm 0.010 \;nm$- wide region at $ x = 1.0 \; \text{nm} $ is given by $$\text{Prob}( \text{in } \delta x \text{ at } x=1.0{\;\rm nm}) = |\psi(1.0)|^2 (0.010)$$ Plugging $\psi(x)$ from the formula above for $x\geq 0$ $$\text{Prob}( \text{in } \delta x \text{ at } x=1.0{\;\rm nm}) = (0.010)\left|(1.414 ) e^{-1.0/(1.0)}\right|^2 $$ $$\text{Prob}( \text{in } \delta x \text{ at } x=1.0{\;\rm nm}) = \bf 0.00271=\color{red}{\bf 0.271\%}$$ $$\color{blue}{\bf [b]}$$ The probability of finding the electron in the interval $ 0.50 \; \text{nm} \leq x \leq 1.50 \; \text{nm} $ is given by $$ P(0.50 \leq x \leq 1.50) = \int_{0.50}^{1.50} |\psi(x)|^2 \; dx\tag 1 $$ where the wave function $ \psi(x) $ for $ x \geq 0 $ is given by: $$ \psi(x) = (1.414 \; \text{nm}^{-1/2}) e^{-x/(1.0 \; \text{nm})} $$ Thus, the square of the wave function is: $$ |\psi(x)|^2 = (1.414)^2 e^{-2x/(1.0 \; \text{nm})} = 2.0 \; e^{-2x} $$ Plug into (1) $$ P(0.50 \leq x \leq 1.50) =2.0 \int_{0.50}^{1.50} e^{-2x} \; dx $$ $$ P(0.50 \leq x \leq 1.50) =2.0\left[-\frac{1}{2} e^{-2x} \right]_{0.50}^{1.50} $$ $$ P(0.50 \leq x \leq 1.50) = -e^{-2x} \bigg|_{0.50}^{1.50} $$ $$ P(0.50 \leq x \leq 1.50) = \left( -e^{-2(1.50)} \right) - \left( -e^{-2(0.50)} \right) $$ $$P(0.50 \leq x \leq 1.50) =\bf0.318=\color{red}{\bf 31.8\%}$$
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