Answer
$20\%,\;10\%$
Work Step by Step
We know that
$$P_A+P_B+P_C+P_D=1$$
Plug the known;
$$0.4+0.3+P_C+P_D=1$$
Hence,
$$ P_C+P_D=0.3\tag 1$$
We are told that $P_C=2P_D$, plug that into (1)
$$ 2P_D+P_D=0.3$$
Thus,
$$P_D=0.1$$
Plug into (1);
And hence,
$$P_D=0.2$$
Therefore, the probabilities of C
$$P_C=\color{red}{\bf 20}\%$$
and the probabilities of C
$$P_D=\color{red}{\bf 10}\%$$