Answer
The increasing order of boiling points is :
$(CH_3)_3C-(CH_3)_3\lt CH_3CH_2C (CH_3)_2CH_2CH_2CH_3 \lt octane$
Work Step by Step
All three alkanes have 8 carbon atoms. So, the boiling point depends on the extent of branching. More branching reduces the boiling point of the compound because of reduced surface area and subsequently lesser intermolecular attraction. The compound with the most branching has the least boiling point. Octane has the highest boiling point of the three since it is straight chained.
