Introductory Chemistry (5th Edition)

Published by Pearson
ISBN 10: 032191029X
ISBN 13: 978-0-32191-029-5

Chapter 18 - Organic Chemistry - Exercises - Questions - Page 682: 6

Answer

a) Tetrahedral geometry b) Trigonal planar geometry c) linear geometry

Work Step by Step

We now the electronic configuration of the carbon is 1$s^{2}$2$s^{2}$2$p^{2}$. It has 1 electron pair in 2s and 2 un-paired electron in the 3 2p orbitals single bond has 1 σ bond. double bond has 1 σ bond and 1 π bond. triple bond has 1 σ bond and 2 π bonds. a) So a carbon with 4 single bonds has the three 2p orbitals and a 2s orbital hybridized to make 4 equivalent s$p^{3}$ hybridzed and thus forms tetrahedral shape geometry. b) similarly , the hybridization here would be s$p^{2}$ and shape will be trigonal planar. c) one single bond and one triple bond - he hybridization here would be s$p^{1}$ and shape will be linear.
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