Introductory Chemistry (5th Edition)

Published by Pearson
ISBN 10: 032191029X
ISBN 13: 978-0-32191-029-5

Chapter 16 - Oxidation and Reduction - Exercises - Problems - Page 605: 89

Answer

Overall reaction for alkaline battery: $Zn(s) + 2MnO_{2} (s) + 2H_{2}O (l) -> Zn(OH)_{2}(s) + 2MnO(OH) (s)$

Work Step by Step

First, write half reactions. Anode reaction (after balancing): $Zn(s) + 2OH^{-} -> Zn(OH)_{2} + 2e^{-}$ Cathode reaction (after balancing): $2MnO_{2} + 2H_{2}O + 2e^{-} -> 2MnO(OH) + 2OH^{-}$ Now, to eliminate e from both the equations, we have to add those two equations. After adding two equations, we get $Zn(s) + 2MnO_{2} (s) + 2H_{2}O (l) -> Zn(OH)_{2}(s) + 2MnO(OH) (s)$ This is the overall reaction that occurs in the alkaline battery.
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