Introductory Chemistry (5th Edition)

Published by Pearson
ISBN 10: 032191029X
ISBN 13: 978-0-32191-029-5

Chapter 15 - Chemical Equilibrium - Exercises - Cumulative Problems - Page 570: 98

Answer

Molar solubility: $5.54 \times 10^{-6} M$ Mass in a saturated solution in 15.0 L: $9.63 \times 10^{-3}g$

Work Step by Step

1. Write the $K_{sp}$ expression: $ FeCO_3(s) \lt -- \gt 1Fe^{2+}(aq) + 1CO_3^{2-}(aq)$ $3.07 \times 10^{-11} = [Fe^{2+}]^ 1[CO_3^{2-}]^ 1$ 2. Considering a pure solution: $[Fe^{2+}] = 1S$ and $[CO_3^{2-}] = 1S$ $3.07 \times 10^{-11}= ( 1S)^ 1 \times ( 1S)^ 1$ $3.07 \times 10^{-11} = S^ 2$ $ \sqrt [ 2] {3.07 \times 10^{-11}} = S$ $5.54 \times 10^{-6} = S$ - This is the molar solubility value for this salt. 3. Find the number of moles: $Concentration(M) = \frac{n(mol)}{V(L)}$ $5.54 \times 10^{-6} = \frac{n(mol)}{15}$ $5.54 \times 10^{-6} * 15 = n(mol)$ $8.31 \times 10^{-5} moles = n(mol)$ 4. Determine the molar mass of this compound ($FeCO_3$): 55.85* 1 + 12.01* 1 + 16* 3 = 115.86g/mol 5. Calculate the mass $mm(g/mol) = \frac{mass(g)}{n(mol)}$ $mm(g/mol) * n(mol) = mass(g)$ $ 115.86 * 8.31 \times 10^{-5} = mass(g)$ $9.63 \times 10^{-3} = mass(g)$
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