General, Organic, and Biological Chemistry: Structures of Life (5th Edition)

Published by Pearson
ISBN 10: 0321967461
ISBN 13: 978-0-32196-746-6

Chapter 11 - Acids and Bases - 11.7 Reactions of Acids and Bases - Questions and Problems - Page 425: 11.55

Answer

a. $ZnCO_3(s) + HBr(aq) \longrightarrow CO_2(g) + H_2O(l) + ZnBr_2(aq)$ b. $Zn(s) + 2HCl(aq) \longrightarrow H_2(g) + ZnCl_2(aq)$ c. $HCl(aq) + NaHCO_3(s) \longrightarrow CO_2(g) + H_2O(l) + NaCl(aq)$ d. $H_2SO_4(aq) + Mg(OH)_2(s) \longrightarrow MgSO_4(aq) + 2H_2O(l)$

Work Step by Step

a. This is a reaction between an acid and a carbonate. First, the Carbonate ion will react with 2 protons from the acid, producing $H_2CO_3$, which will break down into $H_2O(l)$ and $CO_2(g)$. The remaining ions: $Zn^{2+}$ and $Br^-$ will produce a salt: $ZnBr_2$. $ZnCO_3(s) + HBr(aq) \longrightarrow CO_2(g) + H_2O(l) + ZnBr_2(aq)$ b. This is a reaction between an acid and a metal. Therefore, we know that it will produce $H_2(g)$ and a salt made with the metal ion and the conjugate base of the acid. - Metal ion: $Zn^{2+}$ - Conjugate base: $Cl^-$ Resulting salt: $ZnCl_2$ $Zn(s) + HCl(aq) \longrightarrow H_2(g) + ZnCl_2(aq)$ - Balance the equation: $Zn(s) + 2HCl(aq) \longrightarrow H_2(g) + ZnCl_2(aq)$ c. This is a reaction between an acid and a bicarbonate. Thus, we know that it will produce $CO_2(g)$, $H_2O(l)$, using the bicarbonate and a proton from the acid, and a salt with the remaining ions. $HCl(aq) + NaHCO_3(s) \longrightarrow CO_2(g) + H_2O(l) + NaCl(aq)$ d. This is a reaction between an acid and a hydroxide. Therefore, we know that it will produce $H_2O(l)$, with the protons from the acid, and the hydroxide ions. The remaining ions will produce a salt. Remaining ions: $S{O_4}^{2-}$ and $Mg^{2+}$ $H_2SO_4(aq) + Mg(OH)_2(s) \longrightarrow MgSO_4(aq) + H_2O(l)$ - Balance the equation: $H_2SO_4(aq) + Mg(OH)_2(s) \longrightarrow MgSO_4(aq) + 2H_2O(l)$
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