General Chemistry (4th Edition)

Published by University Science Books
ISBN 10: 1891389602
ISBN 13: 978-1-89138-960-3

Chapter 23 Chemical Thermodynamics - Problems - Page 890: 19

Answer

$\Delta S^{\circ}_{rxn}=-429.3\,JK^{-1}mol^{-1}$ $\Delta G^{\circ}_{rxn}=-505\,kJ/mol$ The reaction is spontaneous from left to right.

Work Step by Step

$\Delta S^{\circ}_{rxn}=\Sigma n_{p}S^{\circ}(products)-\Sigma n_{r}S^{\circ}(reactants)$ $=[S^{\circ}(C_{6}H_{6},l)]-[3S^{\circ}(C_{2}H_{2},g)]$ $=173.4\,JK^{-1}mol^{-1}-[3(200.9\,Jmol^{-1}K^{-1})]$ $=-429.3\,Jmol^{-1}K^{-1}=-0.4293\,kJmol^{-1}K^{-1}$ $\Delta G^{\circ}_{rxn}=\Delta H^{\circ}_{rxn}-T\Delta S^{\circ}_{rxn}$ $=-633.1\,kJ/mol-(298\,K\times-0.4293\,kJ/mol\cdot K)$ $=-505\,kJ/mol$ As $\Delta G^{\circ}$ is negative, the reaction is spontaneous from left to right.
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