General Chemistry (4th Edition)

Published by University Science Books
ISBN 10: 1891389602
ISBN 13: 978-1-89138-960-3

Chapter 14 Thermochemistry - Problems - Page 510: 21

Answer

$$3 Fe_2O_3(s) \longrightarrow \frac{1}{2} O_2(g) + 2 Fe_3O_4(s)$$ $ \Delta H^o_{rxn} = 236 \ kJ/mol$

Work Step by Step

1. Reverse the first equation and multiply it by 3: $$3 Fe_2O_3(s) \longrightarrow 6 Fe(s) + \frac{9}{2}O_2(g)$$ $\Delta H^o_{rxn} = (-3)(-824.2 \ kJ/mol) = 2473 \ kJ/mol$ 2. Multiply the second equation by 2: $$6 Fe(s) + 4 O_2(g) \longrightarrow 2 Fe_3O_4(s)$$ $\Delta H^o_{rxn} = (2)(-1118.4 \ kJ/mol) = -2236.8 \ kJ/mol$ 3. Sum the equations: $$3 Fe_2O_3(s) + 6 Fe(s) + 4 O_2(g) \longrightarrow 6 Fe(s) + \frac{9}{2} O_2(g) + 2 Fe_3O_4(s)$$ $$3 Fe_2O_3(s) \longrightarrow \frac{1}{2} O_2(g) + 2 Fe_3O_4(s)$$ $ \Delta H^o_{rxn} = 2473 \ kJ/mol - 2236.8 \ kJ/mol = 236 \ kJ/mol$
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