General Chemistry: Principles and Modern Applications (10th Edition)

Published by Pearson Prentice Hal
ISBN 10: 0132064529
ISBN 13: 978-0-13206-452-1

Chapter 23 - The Transition Elements - 23-1 Concept Assessment - Page 1037: 23-1

Answer

The electron configuration of Fe is $[\mathrm{Ar}] 3 d^{6} 4 \mathrm{s}^{2}$ and for $\mathrm{Fe}^{3+},[\mathrm{Ar}] 3 d^{5} .$ The $3 d^{5}$ subshell, being half-filled, provides stability, which favors the oxidation state of $+3$. Cobalt $\left([\mathrm{Ar}] 3 d^{7} 4 s^{2}\right)$ and nickel $\left([\mathrm{Ar}] 3 d^{8} 4 s^{2}\right)$ must lose four and five electrons, respectively, to achieve a half-filled $3d$ subshell. However, they both lose the 2 electrons in $4S$ subshell (the higher energy subshell in transition metals), yielding the $+2$ oxidation state.

Work Step by Step

Update this answer!

You can help us out by revising, improving and updating this answer.

Update this answer

After you claim an answer you’ll have 24 hours to send in a draft. An editor will review the submission and either publish your submission or provide feedback.