General Chemistry: Principles and Modern Applications (10th Edition)

Published by Pearson Prentice Hal
ISBN 10: 0132064529
ISBN 13: 978-0-13206-452-1

Chapter 19 - Spontaenous Change: Entropy and Gibbs Energy - 19-2 Concept Assessment - Page 827: 19-2

Answer

When the volume of the gas in Figure19-1. is doubled, it is equivalent to multiplying the length of the box L by 2 in Figure19-3a. The gas in Figure 19-1. tends to expand to fill all the available volume. A second explanation for the gas expansion is that the system energy tends to be distributed among the greater possible number of available energy levels in the 2L box compared to its counterpart, the L box.

Work Step by Step

When the volume of the gas in Figure19-1. is doubled, it is equivalent to multiplying the length of the box L by 2 in Figure19-3a. The gas in Figure 19-1. tends to expand to fill all the available volume. A second explanation for the gas expansion is that the system energy tends to be distributed among the greater possible number of available energy levels in the 2L box compared to its counterpart, the L box.
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