General Chemistry 10th Edition

Published by Cengage Learning
ISBN 10: 1-28505-137-8
ISBN 13: 978-1-28505-137-6

Chapter 3 - Calculations with Chemical Formulas and Equations - Questions and Problems - Page 121: 3.65

Answer

the ration of Os atoms to O atoms is 1:4 , therefore the empirical formula of the component is $OsO_{4}$.

Work Step by Step

Strategy: 1- Convert the masses to moles 2- Divide each mole number by the smallest one in order to find the smallest integers. The sample contains 2.16 g osmium (Os) and (2.89-2.16) = 0.73 g oxygen. Converted to moles we will have: Moles of Os: 2.16g$\times\frac{1 mol(Os)}{190 g (Os)}$ = 0.01137 mol Os Moles of oxygen: 0.73g$\times\frac{1 mol (O)}{16.0 g (O) }$ = 0.045625 mol O The smallest mole number is the one of Os. Divide by this smallest number: 0.01137$\div$0.01137 = 1 0.045625$\div$0.01137 = 4.01 we can round this to 4 ( within experimental error) So the ration of Os atoms to O atoms is 1:4 , therefore the empirical formula of the component is $OsO_{4}$
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