General Chemistry 10th Edition

Published by Cengage Learning
ISBN 10: 1-28505-137-8
ISBN 13: 978-1-28505-137-6

Chapter 2 - Atoms, Molecules, and Ions - Questions and Problems - Page 87: 2.152

Answer

CoS$O_{4}$ $\cdot$ 7 $H_{2}$O is the formula for cobalt(II) sulfate heptahydrate. CoS$O_{4}$ $\cdot$ $H_{2}$O is the formula for cobalt(II) sulfate monohydrate. 1.957 g anhydrous cobalt(II) sulfate, with chemical formula CoS$O_{4}$, can be obtained from 3.548 g of heptahydrate CoS$O_{4}$ $\cdot$ 7 $H_{2}$O.

Work Step by Step

CoS$O_{4}$ $\cdot$ 7 $H_{2}$O is the formula for cobalt(II) sulfate heptahydrate. CoS$O_{4}$ $\cdot$ $H_{2}$O is the formula for cobalt(II) sulfate monohydrate. When we heat CoS$O_{4}$ $\cdot$ 7 $H_{2}$O to obtain CoS$O_{4}$ $\cdot$ $H_{2}$O, one water molecule is left while 6 are driven off for each 1 molecule of CoS$O_{4}$ If we write the law of conservation of mass, we would have: m (CoS$O_{4}$ $\cdot$ 7 $H_{2}$O) = m ( CoS$O_{4}$ $\cdot$ $H_{2}$O) + m $H_{2}$O. By subtracting the mass of CoS$O_{4}$ $\cdot$ $H_{2}$O (2.184 g) from the mass of CoS$O_{4}$ $\cdot$ 7 $H_{2}$O (3.548 g), we find the mass of water that has been driven off when we heated CoS$O_{4}$ $\cdot$ 7 $H_{2}$O : m $H_{2}$O = m (CoS$O_{4}$ $\cdot$ 7 $H_{2}$O) - m ( CoS$O_{4}$ $\cdot$ $H_{2}$O) m $H_{2}$O =3.548 g - 2.184 g m $H_{2}$O = 1.364 g water 1.364 g water are given off when CoS$O_{4}$ $\cdot$ 7 $H_{2}$O is heated to obtain CoS$O_{4}$ $\cdot$ $H_{2}$O. Note that there are 6 molecules water driven off in this process, for every one molecule of CoS$O_{4}$ $\cdot$ 7 $H_{2}$O. Note as well that there are 7 molecules of water for 1 molecule CoS$O_{4}$ in CoS$O_{4}$ $\cdot$ 7 $H_{2}$O. So in 3.548 g CoS$O_{4}$ $\cdot$ 7 $H_{2}$O there are 1.591 g water. To get the mass of anhydrous Cobalt(II) sulfate, with chemical formula CoS$O_{4}$, that can be obtained from 3.548 g of heptahydrate, we subtract mass of water from the mass of heptahydrate: 3.548 g - 1.591 g = 1.957 g. So, 1.957 g anhydrous cobalt(II) sulfate, with chemical formula CoS$O_{4}$, can be obtained from 3.548 g of heptahydrate CoS$O_{4}$ $\cdot$ 7 $H_{2}$O.
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