Chemistry: The Molecular Nature of Matter and Change 7th Edition

Published by McGraw-Hill Education
ISBN 10: 007351117X
ISBN 13: 978-0-07351-117-7

Chapter 17 - Problems - Page 769: 17.12

Answer

(a) $4 NO+O_2 \leftrightharpoons 2 N_2O_3$ $$Q_C = \frac{[Products]}{[Reactants]} = \frac{[ N_2O_3 ] ^{ 2 }}{[ NO ] ^{ 4 }[ O_2 ]}$$ (b) $SF_6+ 2SO_3\leftrightharpoons 3 SO_2F_2$ $$Q_C = \frac{[Products]}{[Reactants]} = \frac{[ SO_2F_2 ] ^{ 3 }}{[ SF_6 ][ SO_3 ] ^{ 2 }}$$ (c) $2SClF_5+H_2\leftrightharpoons S_2F_{10}+2HCl$ $$Q_C = \frac{[Products]}{[Reactants]} = \frac{[ S_2F_{10} ][ HCl ] ^{ 2 }}{[ SClF_5 ] ^{ 2 }[ H_2 ]}$$

Work Step by Step

(a) - Balance the reaction. $2 NO+O_2 \leftrightharpoons N_2O_3$ $2 NO+O_2 \leftrightharpoons 2N_2O_3$ $4 NO+O_2 \leftrightharpoons 2 N_2O_3$ - The exponent of each concentration is equal to its balance coefficient. $$Q_C = \frac{[Products]}{[Reactants]} = \frac{[ N_2O_3 ] ^{ 2 }}{[ NO ] ^{ 4 }[ O_2 ]}$$ (b) - Balance the reaction. $SF_6+SO_3\leftrightharpoons SO_2F_2$ $SF_6+SO_3\leftrightharpoons 2 SO_2F_2$ $SF_6+ 2SO_3\leftrightharpoons 2 SO_2F_2$ $SF_6+ 2SO_3\leftrightharpoons 3 SO_2F_2$ - The exponent of each concentration is equal to its balance coefficient. $$Q_C = \frac{[Products]}{[Reactants]} = \frac{[ SO_2F_2 ] ^{ 3 }}{[ SF_6 ][ SO_3 ] ^{ 2 }}$$ (c) - Balance the reaction. $SClF_5+H_2\leftrightharpoons S_2F_{10}+HCl$ $2SClF_5+H_2\leftrightharpoons S_2F_{10}+2HCl$ - The exponent of each concentration is equal to its balance coefficient. $$Q_C = \frac{[Products]}{[Reactants]} = \frac{[ S_2F_{10} ][ HCl ] ^{ 2 }}{[ SClF_5 ] ^{ 2 }[ H_2 ]}$$
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