Chemistry: The Central Science (13th Edition)

Published by Prentice Hall
ISBN 10: 0321910419
ISBN 13: 978-0-32191-041-7

Chapter 21 - Nuclear Chemistry - Exercises - Page 948: 21.35

Answer

6%

Work Step by Step

-Need to use these equations: t($_{1/2}) = $$\frac{ln(2)}{k}$ and ln(N$_{t}$) = ln(N$_{0}$) - kt. -Use the half life formula to find k. t($_{1/2}) = $$\frac{ln(2)}{k}$ = 12.3yr$^{-1}$ k = 0.0564 yr$^{-1}$ -Solve for Nt by plugging in the found and given values. ln(N$_{t}$) = ln(${3.024g}$) - [(0.0564yr$^{-1}$)(50yr)] ln(N$_{t}$) = -1.71 e$^{ln(N_{t})}$ = e$^{-2.71}$ N$_{t}$ = 0.181g -Divide by original mass and multiply by 100% $\frac{0.181g}{3.024g}$ = 0.0598 3.024g is the mass of H multiplied by 3. 0.0598 $\times$ 100% = 5.98% Therefore $\approx$ 6% of the tritium remains meaning that the dial will be dimmed by 94%
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