Chemistry: The Central Science (13th Edition)

Published by Prentice Hall
ISBN 10: 0321910419
ISBN 13: 978-0-32191-041-7

Chapter 20 - Electrochemistry - Exercises - Page 901: 20.25e

Answer

$H_2O + Br^- + 2MnO_4^- \rightarrow BrO_3^- + 2MnO_2 +2OH^-$

Work Step by Step

First, solve it as if it takes place in an acidic solution Half reaction 1: MnO4- —> MnO2 Add 2 H2O on right side, add 4 H+ on left side, add 3e- on left side 3e- +4H+ +MnO4- —>MnO2 +2H2O Half reaction 2: Br- —> BrO3 - Add 3 H2O on left side, add 6H+ on right side, add 6e- on right side 3H2O + Br- —> BrO3- +6H+ + 6e- Reaction 1 times 2 so that e- can be cancelled Get: 2H+ +Br- +2MnO4 —> BrO3- +2MnO2 +H2O Add 2OH- to both the reactants and the products side to neutralize H+, and cancel out water as needed You get: H2O + Br- + 2MnO4- —> BrO3- + 2MnO2 +2OH-
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