Chemistry: The Central Science (13th Edition)

Published by Prentice Hall
ISBN 10: 0321910419
ISBN 13: 978-0-32191-041-7

Chapter 16 - Acid-Base Equilibria - Integrative Exercises - Page 722: 16.117

Answer

Approximately 7.65 ml.

Work Step by Step

1. Find $[H^+]$ $[H^+] = 10^{-pH}$ $[H^+] = 10^{-2.05} = 8.9125 \times 10^{-3}M$ 2. Find the nº of moles of $H^+$ in the solution: $n(moles) = C * V(L)$ $n(moles) = 8.9125 \times 10^{-3} * 10$ $n(moles) = 8.9125 \times 10^{-2}$ 3. Since $HCl$ is a strong acid: $n(moles)(H^+) = n(moles)(HCl)$ 4. Convert that number to grams of $HCl$ $mm(HCl) = 1.01 + 35.45 = 36.46$ $mass(g) = n(moles) * mm$ $mass(g) = 8.9125 \times 10^{-2} * 36.46$ $mass(g) = 3.25g$ 5. Since the initial solution is 36% HCl (mass), we will need; $\frac{36}{100} = \frac{3.25g}{x}$ $36x = 325g$ $x = 9.03g$ 6. Convert that mass to volume, using the density: $V = \frac{mass}{density}$ $V = \frac{9.03}{1.18}$ $V = 7.65 ml$
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