Chemistry: Principles and Practice (3rd Edition)

Published by Cengage Learning
ISBN 10: 0534420125
ISBN 13: 978-0-53442-012-3

Chapter 15 - Solutions of Acids and Bases - Questions and Exercises - Exercises - Page 675: 15.60

Answer

$Ka = 1.418\times 10^{- 3}$

Work Step by Step

1. Drawing the equilibrium (ICE) table, we get these concentrations at equilibrium: \** The image is in the end of this answer. -$[H_3O^+] = [ClCH_2COO^-] = x$ -$[ClCH_2COOH] = [ClCH_2COOH]_{initial} - x$ 2. Calculate the $[H_3O^+]$ $[H_3O^+] = 10^{-pH}$ $[H_3O^+] = 10^{- 1.95}$ $[H_3O^+] = 1.122 \times 10^{- 2}M$ Therefore : $x = 0.01122$ 3. Write the Ka equation, and find its value: $Ka = \frac{[H_3O^+][ClCH_2COO^-]}{ [ClCH_2COOH]}$ $Ka = \frac{x^2}{[InitialClCH_2COOH] - x}$ $Ka = \frac{( 0.01122)^2}{ 0.1- 0.01122}$ $Ka = \frac{ 1.259\times 10^{- 4}}{ 0.08878}$ $Ka = 1.418\times 10^{- 3}$ --------
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