Chemistry: The Molecular Science (5th Edition)

Published by Cengage Learning
ISBN 10: 1285199049
ISBN 13: 978-1-28519-904-7

Chapter 15 - Additional Aqueous Equilibria - Exercise 15.2 - Blood pH - Page 658: a

Answer

$pH = 7.423$

Work Step by Step

1. Calculate the pKa Value $pKa = -log(Ka)$ $pKa = -log( 6.3 \times 10^{- 8})$ $pKa = 7.201$ 2. Check if the ratio is between 0.1 and 10: - $\frac{[Base]}{[Acid]} = \frac{2.5 \times 10^{-3}}{1.5 \times 10^{-3}} = 1.667$ : It is. 3. Check if the compounds exceed the $K_a$ by 100 times or more: - $ \frac{2.5 \times 10^{-3}}{ 6.3 \times 10^{-8}} = 3.968\times 10^{4}$ - $ \frac{1.5 \times 10^{-3}}{ 6.3 \times 10^{-8}} = 2.381\times 10^{4}$ 4. Using the Henderson–Hasselbalch equation: $pH = pKa + log(\frac{[Base]}{[Acid]})$ $pH = 7.201 + log(\frac{2.5 \times 10^{-3}}{1.5 \times 10^{-3}})$ $pH = 7.201 + 0.2218$ $pH = 7.423$
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