Chemistry: Atoms First (2nd Edition)

Published by Cengage Learning
ISBN 10: 1305079248
ISBN 13: 978-1-30507-924-3

Chapter 4 - Exercises - Page 197e: 62

Answer

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Work Step by Step

a. Overlap of 1s atomic orbitals of two hydrogen atoms: The overlap of 1s atomic orbitals of two hydrogen atoms forms a molecular orbital. This molecular orbital is a sigma (σ) bond, which is a type of bonding orbital. The σ bond is formed by the constructive interference of the wavefunctions of the two 1s atomic orbitals. b. Overlap of 2p atomic orbitals of two carbon atoms: The overlap of 2p atomic orbitals of two carbon atoms forms multiple molecular orbitals. These molecular orbitals include: - Sigma (σ) bonds: Formed by the constructive interference of the wavefunctions of the 2p atomic orbitals along the internuclear axis. - Pi (π) bonds: Formed by the constructive interference of the wavefunctions of the 2p atomic orbitals perpendicular to the internuclear axis. c. Overlap of 3d atomic orbitals of two transition metal atoms: The overlap of 3d atomic orbitals of two transition metal atoms forms multiple molecular orbitals. These molecular orbitals include: - Sigma (σ) bonds: Formed by the constructive interference of the wavefunctions of the 3d atomic orbitals along the internuclear axis. - Pi (π) bonds: Formed by the constructive interference of the wavefunctions of the 3d atomic orbitals perpendicular to the internuclear axis. d. Overlap of 4f atomic orbitals of two lanthanide atoms: The overlap of 4f atomic orbitals of two lanthanide atoms forms multiple molecular orbitals. These molecular orbitals include: - Sigma (σ) bonds: Formed by the constructive interference of the wavefunctions of the 4f atomic orbitals along the internuclear axis. - Pi (π) bonds: Formed by the constructive interference of the wavefunctions of the 4f atomic orbitals perpendicular to the internuclear axis.
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