Chemistry: Atoms First (2nd Edition)

Published by Cengage Learning
ISBN 10: 1305079248
ISBN 13: 978-1-30507-924-3

Chapter 2 - Challenge Problems - Page 99i: 166

Answer

See the explanation

Work Step by Step

a. Neat hypothetical - if $m_s$ had three possible values (instead of the usual two), each orbital could hold three electrons. From that everything else follows:. Number of orbitals in shell: $n=n^2$ Electrons per orbital (hypothetical) $ = 3$ So capacity of shell $n=3n^2$ How many electrons would an orbital be able to hold? $3$ electrons (one for each allowed $m_s$) b. The first period will contain: $3(1^2)=3$ elements The second period will contain: $3(2^2)=12$ elements c. Let's count the elements in the first transition-metal series: $l=2\Rightarrow 5$ orbitals $\Rightarrow 5\times 3=15$ elements d. Let's count the number of electrons the set of 4f orbitals would hold: $l=3\Rightarrow 7$ orbitals $\Rightarrow 7\times 3=21$ electrons
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