Chemistry: Atoms First (2nd Edition)

Published by Cengage Learning
ISBN 10: 1305079248
ISBN 13: 978-1-30507-924-3

Chapter 2 - Challenge Problems - Page 99i: 164

Answer

See the explanation

Work Step by Step

The nodes of a wave function are the points where the wave function goes to zero. For the given wave function \( \psi_{300} \), the position of the nodes can be found by setting the wave function equal to zero and solving for \( \sigma \). Setting \( \psi_{300} \) equal to zero gives: \[ \frac{1}{81 \sqrt{3 \pi}}\left(\frac{1}{a_{0}}\right)^{3 / 2}\left(27-18 \sigma+2 \sigma^{2}\right) e^{-\sigma / 3} = 0 \] Since the exponential term is never zero, we can focus on the polynomial part: \[ \left(27-18 \sigma+2 \sigma^{2}\right) = 0 \] Solving this quadratic equation gives the values of \( \sigma \) at which the wave function goes to zero. The solutions are: \[ \sigma = \frac{18\pm\sqrt{324-216}}{4}=\frac{9\pm3\sqrt 3}{2} \] $\sigma_1\approx 1.9$ $\sigma_2\approx 7.1$ We can find the positions of the nodes in terms of the Bohr radius: $r_1 = \sigma_1a_{0}=1.9\times 5.29\times 10^{-11}\approx 1.005\times 10^{-10}\text{ m}$ $r_2 = \sigma_2a_{0}=7.1\times 5.29\times 10^{-11}\approx 3.756\times 10^{-10}\text{ m}$
Update this answer!

You can help us out by revising, improving and updating this answer.

Update this answer

After you claim an answer you’ll have 24 hours to send in a draft. An editor will review the submission and either publish your submission or provide feedback.