Chemistry: Atoms First (2nd Edition)

Published by Cengage Learning
ISBN 10: 1305079248
ISBN 13: 978-1-30507-924-3

Chapter 19 - Review Questions - Page 789: 6

Answer

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Work Step by Step

Silicon carbide (SiC) is a covalent compound with a crystal structure resembling a diamond lattice. It consists of silicon (Si) atoms bonded to carbon (C) atoms in a tetrahedral arrangement, forming a network of strong covalent bonds. Proposed Structure of SiC Crystal type: SiC crystallizes in a tetrahedral lattice. Each Si atom is covalently bonded to 4 C atoms, and each C atom is bonded to 4 Si atoms, forming a 3D network. This is analogous to diamond, where each C is tetrahedrally bonded to 4 C atoms, but here the lattice alternates Si and C atoms. Bonding: All bonds are strong covalent bonds (Si–C). This network is responsible for SiC’s extreme hardness, high melting point, and chemical stability. Polymorphs: SiC exists in many polytypes (different stacking sequences of Si–C layers), e.g., 3C-SiC (zinc blende structure), 4H-SiC, and 6H-SiC. Diagram (schematic, tetrahedral) (see graph) Each Si is tetrahedrally bonded to 4 C atoms, and each C to 4 Si atoms. This extends infinitely in 3D.
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