Chemistry: Atoms First (2nd Edition)

Published by Cengage Learning
ISBN 10: 1305079248
ISBN 13: 978-1-30507-924-3

Chapter 13 - Exercises - Page 575f: 132

Answer

a. $I{O_3}^-$ b. $N{O_2}^-$ c. $OI^-$

Work Step by Step

These compounds are conjugate bases of oxyacids; therefore, we can compare the strength of each one: - Remember, the weaker the acid, the stronger its conjugate base. a. $HIO_3$ and $HBrO_3$: $HIO_3$ is weaker.** Therefore: $I{O_3}^-$ is the stronger conjugate base. b. $HNO_2$ and $HNO_3$: $HNO_2$ is weaker.*** Therefore: $N{O_2}^-$ is the stronger conjugate base. c. $HOCl$ and $HOI$: $HOI$ is weaker. ** Therefore: $IO^-$ is the stronger conjugate base. ** The one with the most electronegative central atom is the stronger one. *** The one with the greater number of oxygens is the stronger one.
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