Chemistry: A Molecular Approach (3rd Edition)

Published by Prentice Hall
ISBN 10: 0321809246
ISBN 13: 978-0-32180-924-7

Chapter 24 - Sections 24.1-24.6 - Exercises - Review Questions - Page 1125: 15

Answer

Almost all tetrahedral complexes are high-spin because of their reduced ligand-metal interactions. The d orbits in a tetrahedral complex interact only with four ligands, rather than the six that are in the octahedral complex. As a result, the value of $\Delta$ is generally smaller.

Work Step by Step

Almost all tetrahedral complexes are high-spin because of their reduced ligand-metal interactions. The d orbits in a tetrahedral complex interact only with four ligands, rather than the six that are in the octahedral complex. As a result, the value of $\Delta$ is generally smaller.
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