Chemistry: A Molecular Approach (3rd Edition)

Published by Prentice Hall
ISBN 10: 0321809246
ISBN 13: 978-0-32180-924-7

Chapter 21 - Sections 21.1-21.7 - Exercises - Problems by Topic - Page 1030: 41

Answer

A Has 5 chiral carbons. B has 3 chiral carbons. C has 1 chiral carbon. D has 3 chiral carbons

Work Step by Step

A chiral carbon has four different groups bonded to it. In part a, carbon number 1-5 are all chiral but carbon number 6 is not chiral because two C-H bonds are present. In part b, carbon number 1 is not chiral because it has double bond and only three different groups attached. Carbon number 2-4 are all chiral. Carbon number 5 is not chiral due to the presence of two C-H bonds. In part c, only carbon number 3 is chiral. Carbon number 1 and 4 are not chiral due to the presence of two C-H bonds. Carbon number 2 is not chiral due to the presence of a double bond and only 3 different groups bonded to carbon atom. In part d, carbon number 1-3 are all chiral. Carbon number 4 is not chiral due to the presence of two C-H bonds.
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