Chemistry 9th Edition

Published by Cengage Learning
ISBN 10: 1133611095
ISBN 13: 978-1-13361-109-7

Chapter 4 - Types of Chemical Reactions and Solution Stoichiometry - Exercises - Page 183: 54

Answer

Because no precipitates formed upon addition of NaCl or Na2SO4, we can conclude that Hg22+ and Ba2+ are not present in the sample because Hg2Cl2 and BaSO4 are insoluble salts. However, Mn2+ may be present since Mn2+ does not form a precipitate with either NaCl or Na2SO4. A precipitate formed with NaOH; the solution must contain Mn2+ because it forms a precipitate with OH− [Mn(OH)2(s)].

Work Step by Step

Because no precipitates formed upon addition of NaCl or Na2SO4, we can conclude that Hg22+ and Ba2+ are not present in the sample because Hg2Cl2 and BaSO4 are insoluble salts. However, Mn2+ may be present since Mn2+ does not form a precipitate with either NaCl or Na2SO4. A precipitate formed with NaOH; the solution must contain Mn2+ because it forms a precipitate with OH− [Mn(OH)2(s)].
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