Chemistry 10th Edition

Published by Brooks/Cole Publishing Co.
ISBN 10: 1133610668
ISBN 13: 978-1-13361-066-3

Chapter 4 - The Structure of Atoms - Exercises - Quantum Numbers and Atomic Orbitals - Page 168: 84

Answer

a) $6$ b) $10$ c) $0$ d) $2$ e) $1$

Work Step by Step

a) If $n=3$ and $l=1$, there are three possible values for magnetic quantum number: $−1$, $0$ and $1$, and for every of these options there are two possible spin quantum numbers ($+\frac{1}{2}$ and $−\frac{1}{2}$). In total, there are $3×2=6$ electrons which have the required values of principal and angular quantum number. b) If $n=3$ and $l=2$, allowed values for magnetic quantum number, $m_{l}$, are: $-2$, $-1$, $0$, $1$ and $2$. For each of these options, there are two possible spin quantum numbers ($+\frac{1}{2}$ and $−\frac{1}{2}$). In total, there are $5\times2=10$ electrons which have the required values of principal and angular quantum number. c) There are $0$ electrons with this combination of quantum numbers, because magnetic quantum number is not in the allowed range, which is between $-l$ and $l$. Since $l=0$, the only option for magnetic quantum number would be $m_{l}=0$. d) Since principal, angular and magnetic quantum numbers are all in the allowed range of values, there are only $2$ electrons with this combination of quantum numbers (one of these electrons has spin quantum number equal to $+\frac{1}{2}$, and the other one equal to $-\frac{1}{2}$). e) Since all of the quantum numbers given are correct (in terms of allowed range), there can be only one electron with such combination.
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