Chemistry 10th Edition

Published by Brooks/Cole Publishing Co.
ISBN 10: 1133610668
ISBN 13: 978-1-13361-066-3

Chapter 25 - Coordination Compounds - Exercises - Structures of Coordination Compounds - Page 1013: 38

Answer

Isomers are substances that have the same number and kinds of atoms, but arranged differently. Constitutional (structural) isomers, as applied to coordination compounds, are isomers whose differences involve having more than a single coordination sphere or different donor atoms on the same ligand. They contain different atom-to-atom bonding sequences. Stereoisomers, on the other hand, are isomers that differ only in the way that atoms are oriented in space, and therefore involve only one coordination sphere and the same ligands and donor atoms.

Work Step by Step

Isomers are substances that have the same number and kinds of atoms, but arranged differently. Constitutional (structural) isomers, as applied to coordination compounds, are isomers whose differences involve having more than a single coordination sphere or different donor atoms on the same ligand. They contain different atom-to-atom bonding sequences. Stereoisomers, on the other hand, are isomers that differ only in the way that atoms are oriented in space, and therefore involve only one coordination sphere and the same ligands and donor atoms.
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