Chemistry 10th Edition

Published by Brooks/Cole Publishing Co.
ISBN 10: 1133610668
ISBN 13: 978-1-13361-066-3

Chapter 20 - Ionic Equilibria III: The Solubility Product Principle - Exercises - Uses of Solubility Product Constants - Page 798: 17

Answer

1 liter of this solution has $1.342 \times 10^{-7} moles$ of $Pb^{2+}$

Work Step by Step

1. Write the $K_{sp}$ expression: $ PbCrO_4(s) \lt -- \gt 1Cr{O_4}^{2-}(aq) + 1Pb^{2+}(aq)$ $1.8 \times 10^{-14} = [Cr{O_4}^{2-}]^ 1[Pb^{2+}]^ 1$ 2. Considering a pure solution: $[Cr{O_4}^{2-}] = 1x$ and $[Pb^{2+}] = 1x$ $1.8 \times 10^{-14}= ( 1x)^ 1 \times ( 1x)^ 1$ $1.8 \times 10^{-14} = 1x^ 2$ $1.8 \times 10^{-14} = x^ 2$ $ \sqrt [ 2] {1.8 \times 10^{-14}} = x$ $1.342 \times 10^{-7} = x$ - This is the molar solubility value for this salt. - Therefore, one saturated solution of this salt has $1.342 \times 10^{-7}M PbCrO_4$. Which means: 1 Liter of solution = $1.342 \times 10^{-7} moles$ of $Pb^{2+}$
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