Answer
$3\pi$; $-\pi$
Work Step by Step
Coterminal angles differ by a multiple of $2\pi$ radians. So, we can add $2\pi$ radians to get a positive angle that is coterminal with $\pi$ radians.
$\pi+2\pi=3\pi$
We can subtract $2\pi$ radians to get a negative angle that is coterminal with $\pi$ radians.
$\pi-2\pi=-\pi$