Answer
The statement is inferential.
Work Step by Step
Through the data given, we know that there are $4776$ answers having been given to the question, so a sample of college students have been asked to answer the question.
Yet, in the statement, the representative had generalized that $52.7\%$ of ALL college students always wear a seat belt. How can we generalize like that? He had taken the data from $2518$ 'Always' answers among $4776$ answers received to make such a statement for all college students.
So, this must be an inferential statement.