Answer
The set $W$ is not a subspace of $ R^{3}$.
Work Step by Step
Let $A$ be a fixed $2\times3$ matrix and $x, y\in W$, then $Ax=[\begin{array} \\1 \\2
\end{array}]$ and $Ay=[\begin{array} \\1 \\2
\end{array}]$
Thus we have that $A(x+y)=Ax+Ay=[\begin{array} \\2 \\4
\end{array}]\ne [\begin{array} \\1 \\2
\end{array}] $
Therefore $ x+y \notin W$
Therefore the set $W$ is not a subspace of $ R^{3}$.