Answer
it is a vector space.
Work Step by Step
Any $3\times 3$ upper triangular matrix takes the form
$$\left[ \begin {array}{cccc} a&b&c\\ 0&d&e
\\ 0&0&f
\end {array} \right], \quad a,b,c,d,e,f\in R$$
It is easy to note that the set of all $3\times 3$ upper triangular matrices contains the zero vector and closed under the standard addition and scalar multiplication. Strightforward calculations show that it is a vector space.