Answer
True
Work Step by Step
Assume that $A$ is an invertible $n × n$ matrix and nullspace (A) = colspace (A)
$A$ is invertible $\rightarrow nullspace (A)=0 \rightarrow colspace (A)=0$
Thus, $A$ is a null matrix.
Since null matrix is non-invertible matrix, $A$ can not be an invertible matrix.
Hence, the statement is true.