University Physics with Modern Physics (14th Edition)

Published by Pearson
ISBN 10: 0321973615
ISBN 13: 978-0-32197-361-0

Chapter 20 - The Second Law of Thermodynamics - Problems - Exercises - Page 678: 20.29

Answer

See explanation.

Work Step by Step

(a) $f(v) = 4\pi \frac{m}{2 \pi kT} v^2 e^{-mv^2/2kT}$ The velocity distribution depends only on T, so in an isothermal process it does not change. (b) $\Delta S = k ln \frac{w_2}{w_1} $ Where $ 3V \space is \space w_2 = (3)N w_1$ So $\Delta S = k ln (3)^N $ $\Delta S =N k ln (3) $ $\Delta S =nN_A k ln (3) $ $\Delta S =nR ln (3) $ $\Delta S =(2.00 mol)(8.3145 J/mol⋅K)ln(3) $ $\Delta S = +18.3 J/K$ (c) $Q = nRT ln (\frac{V_2}{V_1}) $ $\Delta S = Q/T$ So $\Delta S = nR ln (\frac{V_2}{V_1})$ $\Delta S = (2.00 mol)(8.3145 J/mol ⋅K) ln (\frac{3V_1}{V_1})$ $\Delta S = +18.3 J/K$ The result obtained in (b) are the same
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