General Chemistry: Principles and Modern Applications (10th Edition)

Published by Pearson Prentice Hal
ISBN 10: 0132064529
ISBN 13: 978-0-13206-452-1

Chapter 18 - Solubility and Complex-Ion Equilibria - 18-5 Concept Assessment - Page 799: 18-5

Answer

(a) At $PH=10$, $[OH^-]=1\times10^{-4}$ and $[Mg^{2+}]=1.8\times10^{-3}$ (b) At $PH=5$, $[OH^-]=1\times10^{-9}$ and $[Mg^{2+}]=1.8\times10^{7}$ Comment: In case of (a), the result is plausible, unlike being impossible in case of (b) because the solution is not one of $Mg(OH)_2$ but $MgCl_2{_{(aq.)}}$; $[Mg^{+2}]$, in this case, depends on the solubility of $MgCl_2$.

Work Step by Step

(a) At $PH=10$, $[OH^-]=1\times10^{-4}$ and $[Mg^{2+}]=1.8\times10^{-3}$ (b) At $PH=5$, $[OH^-]=1\times10^{-9}$ and $[Mg^{2+}]=1.8\times10^{7}$ Comment: In case of (a), the result is plausible, unlike being impossible in case of (b) because the solution is not one of $Mg(OH)_2$ but $MgCl_2{_{(aq.)}}$; $[Mg^{+2}]$, in this case, depends on the solubility of $MgCl_2$.
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