Chemistry: The Central Science (13th Edition)

Published by Prentice Hall
ISBN 10: 0321910419
ISBN 13: 978-0-32191-041-7

Chapter 17 - Additional Aspects of Aqueous Equilibria - Exercises - Page 771: 17.79c

Answer

See work below.

Work Step by Step

To determine the procedure, we need to rely on the classification of 5 groups of cations to find the difference between $Mg^{2+}$ and $K^{+}$. $Mg^{2+}$ is a group 4 cation, which has an insoluble phosphate, while $K^{+}$ is a group 5 cation, which remains in the solution after adding the phosphates. Therefore, we are able to setup the procedure: First, add ammonium hydrogen phosphate ($(NH_4)_2HPO_4$) and $NH_3$ to the solution; $MgNH_4PO_4$ would precipitate. Then, filtration of the solution will give us the filtrate consists largely $K^{+}$ ions, while the residue will be the mentioned precipitate.
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