Chemistry: The Molecular Science (5th Edition)

Published by Cengage Learning
ISBN 10: 1285199049
ISBN 13: 978-1-28519-904-7

Chapter 6 - Covalent Bonding - Questions for Review and Thought - Topical Questions - Page 283b: 29c

Answer

P-O

Work Step by Step

Since Oxygen has a higher electronegativity than Sulfur, it will pull on the electrons harder than Sulfur will. Thus, it follows that the bond length for P-O is shorter.
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