Chemistry: Molecular Approach (4th Edition)

Published by Pearson
ISBN 10: 0134112830
ISBN 13: 978-0-13411-283-1

Chapter 15 - Exercises - Page 714: 28

Answer

(a) $Kp=1.483×10^{3}$ Products are favored at equilibrium. (b) $Kp$=$1.0648×10^{19}$ Products are favored at equilibrium. (c)$Kp=2.066×10^{-13}$ Reactants are favored at equilibrium.

Work Step by Step

(a) It is observed,all the coefficients of that reaction were divided by 2 (or multiplied by$\frac{1}{2}$ ). Thus, the new equilibrium constant is equal to the old one to the power of $\frac{1}{2}$. $Kp$=$(2.2×10^{6})$$^{\frac{1}{2}}$=$1.483×10^{3}$ Since $Kp>1$,the products will be favored at equilibrium. (b) It is observed,all the coefficients of that reaction were multiplied by 3.Thus, the new equilibrium constant is equal to the old one to the power of 3 $Kp$=$(2.2×10^{6})$$^{3}$= $1.0648×10^{19}$ Since $Kp>1$,the products will be favored at equilibrium. (c) Since the reaction was inverted and also multiplied by 2, the new equilibrium constant will be equal to the multiplicative inverse of the square of original one. $Kp$=$\frac{1}{(2.2\times10^{6})^{2}}$=$2.066×10^{-13}$ Since $Kp<1$ ,the reactants will be favored at equilibrium.
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